Publication Details |
Category | Text Publication |
Reference Category | Journals |
DOI | 10.1016/j.envpol.2007.10.037 |
Title (Primary) | Calibration of the Chemcatcher® passive sampler for monitoring selected polar and semi-polar pesticides in surface water |
Author | Gunold, R.; Schäfer, R.B.; Paschke, A.; Schüürmann, G.; Liess, M. |
Source Titel | Environmental Pollution |
Year | 2008 |
Department | OEC; OEKOTOX |
Volume | 155 |
Issue | 1 |
Page From | 52 |
Page To | 60 |
Language | englisch |
Keywords | Pesticides; Passive sampling; Water; Bioavailability; Chemcatcher® |
Abstract | Passive sampling is a powerful method for continuous pollution monitoring, but calibration experiments are still needed to generate sampling rates in order to estimate water concentrations for polar compounds. We calibrated the Chemcatcher® device with an uncovered SDB-XC Empore disk as receiving phase for 12 polar and semi-polar pesticides in aquatic environments in flow-through tank experiments at two water flow velocities (0.135 m/s and 0.4 m/s). In the 14-day period of exposure the uptake of test substances in the sampler remained linear, and all derived sampling rates Rs were in the range of 0.1 to 0.5 L/day. By additionally monitoring the release of two preloaded polar pesticides from the SDB-XC disks over time, very high variation in release kinetics was found, which calls into question the applicability of performance reference compounds. Our study expands the applicability of the Chemcatcher® for monitoring trace concentrations of pesticides with frequent occurrence in water.We calibrated the Chemcatcher® passive sampler for current-use polar pesticides in surface waters, allowing its application in future monitoring studies. |
Persistent UFZ Identifier | https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=977 |
Gunold, R., Schäfer, R.B., Paschke, A., Schüürmann, G., Liess, M. (2008): Calibration of the Chemcatcher® passive sampler for monitoring selected polar and semi-polar pesticides in surface water Environ. Pollut. 155 (1), 52 - 60 10.1016/j.envpol.2007.10.037 |