Publication Details

Category Text Publication
Reference Category Journals
DOI 10.1016/j.envpol.2007.10.037
Title (Primary) Calibration of the Chemcatcher® passive sampler for monitoring selected polar and semi-polar pesticides in surface water
Author Gunold, R.; Schäfer, R.B.; Paschke, A.; Schüürmann, G.; Liess, M.
Source Titel Environmental Pollution
Year 2008
Department OEC; OEKOTOX
Volume 155
Issue 1
Page From 52
Page To 60
Language englisch
Keywords Pesticides; Passive sampling; Water; Bioavailability; Chemcatcher®
Abstract Passive sampling is a powerful method for continuous pollution monitoring, but calibration experiments are still needed to generate sampling rates in order to estimate water concentrations for polar compounds. We calibrated the Chemcatcher® device with an uncovered SDB-XC Empore disk as receiving phase for 12 polar and semi-polar pesticides in aquatic environments in flow-through tank experiments at two water flow velocities (0.135 m/s and 0.4 m/s). In the 14-day period of exposure the uptake of test substances in the sampler remained linear, and all derived sampling rates Rs were in the range of 0.1 to 0.5 L/day. By additionally monitoring the release of two preloaded polar pesticides from the SDB-XC disks over time, very high variation in release kinetics was found, which calls into question the applicability of performance reference compounds. Our study expands the applicability of the Chemcatcher® for monitoring trace concentrations of pesticides with frequent occurrence in water.We calibrated the Chemcatcher® passive sampler for current-use polar pesticides in surface waters, allowing its application in future monitoring studies.
Persistent UFZ Identifier https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=977
Gunold, R., Schäfer, R.B., Paschke, A., Schüürmann, G., Liess, M. (2008):
Calibration of the Chemcatcher® passive sampler for monitoring selected polar and semi-polar pesticides in surface water
Environ. Pollut. 155 (1), 52 - 60 10.1016/j.envpol.2007.10.037