Publication Details

Category Text Publication
Reference Category Journals
DOI 10.1016/S0048-9697(97)00133-2
Title (Primary) Physical and chemical characterization of a complexly contaminated scrubber dust - A by-product of copper smelting in Sachsen-Anhalt, Germany
Author Weiß, H. ORCID logo ; Morency, M.; Freyer, K.; Bourne, J.; Fontaine, D.; Ghaleb, B.; Mineau, R.; Möder, M.; Morgenstern, P.; Popp, P.; Preda, M.; Treutler, H.-C.; Wennrich, R.
Source Titel Science of the Total Environment
Year 1997
Department ANA; GWS; SANA
Volume 203
Issue 1
Page From 65
Page To 78
Language englisch
Keywords industrial residue; Germany; scrubber dust; galena; sphalerite; characterization
Abstract

A physical and chemical description of a scrubber dust slurry, known as Theisenschlamm, is presented. This material is generated as a by-product during extraction of copper from a mineralized Permian black shale (Kupferschiefer) in Sachsen-Anhalt, Germany. The Theisenschlamm consists of sulphide grains which are a complex solid solution of Pb, Zn, Cu and Fe. The crystal structures are modified forms of galena and sphalerite/wurtzite. Variations in the X-ray diffraction peak positions of these minerals reflect the poorly developed lattice structures of these phases. Anglesite is a secondary phase. The Theisenschlamm contains 18% Zn and 14% Pb as well as significant concentrations of PAH, PCDD and other organic compounds, rare metals and radionuclides (e.g. 210Po and 210Pb). The original particles have a median diameter of 1.25 μm, however, these particles are themselves aggregates of still smaller particles, typically of submicron size.

Weiß, H., Morency, M., Freyer, K., Bourne, J., Fontaine, D., Ghaleb, B., Mineau, R., Möder, M., Morgenstern, P., Popp, P., Preda, M., Treutler, H.-C., Wennrich, R. (1997):
Physical and chemical characterization of a complexly contaminated scrubber dust - A by-product of copper smelting in Sachsen-Anhalt, Germany
Sci. Total Environ. 203 (1), 65 - 78 10.1016/S0048-9697(97)00133-2