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Title (Primary) Membrane based measurement technology for in situ monitoring of gases in soil
Author Lazik, D.; Ebert, S.; Leuthold, M.; Hagenau, J.; Geistlinger, H.
Journal Sensors
Year 2009
Department BOPHY
Volume 9
Issue 2
Page From 756
Page To 767
Language englisch
Keywords Green house gases; CO2-sequestration; Gas; Monitoring; Membrane; Perm-selectivity
Abstract The representative measurement of gas concentration and fluxes in heterogeneous soils is one of the current challenges when analyzing the interactions of biogeochemical processes in soils and global change. Furthermore, recent research projects on CO2-sequestration have an urgent need of CO2-monitoring networks. Therefore, a measurement method based on selective permeation of gases through tubular membranes has been developed. Combining the specific permeation rates of gas components for a membrane and Dalton's principle, the gas concentration (or partial pressure) can be determined by the measurement of physical quantities (pressure or volume) only. Due to the comparatively small permeation constants of membranes, the influence of the sensor on its surrounding area can be neglected. The design of the sensor membranes can be adapted to the spatial scale from the bench scale to the field scale. The sensitive area for the measurement can be optimized to obtain representative results. Furthermore, a continuous time-averaged measurement is possible where the time for averaging is simply controlled by the wall-thickness of the membrane used. The measuring method is demonstrated for continuous monitoring of O2 and CO2 inside of a sand filled Lysimeter. Using three sensor planes inside the sand pack, which were installed normal to the gas flow direction and a reference measurement system, we demonstrate the accuracy of the gas-detection for different flux-based boundary conditions.
Persistent UFZ Identifier https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=360
Lazik, D., Ebert, S., Leuthold, M., Hagenau, J., Geistlinger, H. (2009):
Membrane based measurement technology for in situ monitoring of gases in soil
Sensors 9 (2), 756 - 767