Publication Details |
Category | Text Publication |
Reference Category | Journals |
DOI | 10.1002/bbpc.19930970909 |
Title (Primary) | Diffusion coefficients, viscosities and densities in the binary subsystems of Methyl isopropyl ketone-n-Butyl acetate-Water |
Author | Thiel, P.; Paschke, A.; Winkelmann, J. |
Source Titel | Berichte der Bunsen-Gesellschaft für physikalische Chemie |
Year | 1993 |
Department | OEC; COE |
Volume | 97 |
Issue | 9 |
Page From | 1119 |
Page To | 1124 |
Language | englisch |
Abstract |
The concentration dependence of mutual diffusion coefficients, kinematic viscosities and densities in the binary systems Methyl isopropyl ketone (Mipk)-n-Butyl acetate (Buac), Buac-Water and Mipk-Water is determined at 288.15 K, 293.15 K and 298.16 K. Diffusion coefficients at infinite dilution were extrapolated from the experimental data. Only in the completely miscible system Mipk-Buac were the heat of mixing at 297.76 K and vapour-liquid equilibrium data at 323.15 K and 343.15 K measured and parameters for the NRTL-equation calculated. In the system Mipk-water with limited miscibility, the NRTL-parameters were obtained from liquid-liquid equilibrium data. Using our values at infinite dilution the concentration dependence of the mutual diffusion coefficients can be satisfactorily predicted by the Caldwell/Babb correlation. |
Persistent UFZ Identifier | https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=27907 |
Thiel, P., Paschke, A., Winkelmann, J. (1993): Diffusion coefficients, viscosities and densities in the binary subsystems of Methyl isopropyl ketone-n-Butyl acetate-Water Ber. Bunsenges. Phys. Chem. 97 (9), 1119 - 1124 10.1002/bbpc.19930970909 |