Publication Details |
| Category | Text Publication |
| Reference Category | Journals |
| DOI | 10.1002/slct.202301823 |
Licence  |
|
| Title (Primary) | Electrochemical cellobiose valorization: Anodic oxidation to cellobionic acid and cathodic reduction to cellobitol |
| Author | Chávez Morejón, M.; Kurig, N.; Tschauder, Y.S.; Harnisch, F.
; Palkovits, R. |
| Source Titel | ChemistrySelect |
| Year | 2023 |
| Department | UMB |
| Volume | 8 |
| Issue | 27 |
| Page From | e202301823 |
| Language | englisch |
| Topic | T7 Bioeconomy |
| Supplements | https://chemistry-europe.onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1002%2Fslct.202301823&file=slct202301823-sup-0001-misc_information.pdf |
| Keywords | bio-based feedstock; cellobiose valorization, electrocatalysis; electrochemical hydrogenation; organic electrosynthesis |
| Abstract | This study elucidates key parameters allowing the electrochemical valorization of cellobiose, by creating value-added products by both, anodic oxidation, and cathodic reduction. We demonstrate the first electrochemical reduction of cellobiose to cellobitol in a divided cell using Pb as cathode, leading up to 49 % conversion, though with long reaction times (over 26 h) and low coulombic efficiency (CE) of 4 %. The successful synthesis of cellobionic acid was demonstrated by mediated oxidation in an undivided electrochemical cell, using a graphite anode and CaBr2 as electrocatalytic mediator. Cellobiose oxidation was highly selective, allowing for up to 92 % conversion to cellobionic acid at 48 % CE when using a charge of 2 FE. |
| Persistent UFZ Identifier | https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=27227 |
| Chávez Morejón, M., Kurig, N., Tschauder, Y.S., Harnisch, F., Palkovits, R. (2023): Electrochemical cellobiose valorization: Anodic oxidation to cellobionic acid and cathodic reduction to cellobitol ChemistrySelect 8 (27), e202301823 10.1002/slct.202301823 |
|