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Title (Primary) Disparate seasonal nitrate export from nested heterogeneous subcatchments revealed with StorAge Selection functions
Author Nguyen, V.T.; Kumar, R.; Musolff, A.; Lutz, S.R.; Sarrazin, F.; Attinger, S.; Fleckenstein, J.H.
Journal Water Resources Research
Year 2022
Department CHS; HDG
Volume 58
Issue 3
Page From e2021WR030797
Language englisch
Topic T5 Future Landscapes
Supplements https://agupubs.onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1029%2F2021WR030797&file=2021WR030797-sup-0001-Supporting+Information+SI-S01.docx
https://agupubs.onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1029%2F2021WR030797&file=2021WR030797-sup-0002-Table+SI-S01.xlsx
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Keywords catchment nitrate export; StorAge Selection fucntion; travel time distribution; mesoscale heterogeneous catchment; subcatchment response
Abstract Understanding catchment controls on catchment solute export is a prerequisite for water quality management. StorAge Selection (SAS) functions encapsulate essential information about catchment functioning in terms of discharge selection preference and solute export dynamics. However, they lack information on the spatial origin of solutes when applied at the catchment scale, thereby limiting our understanding of the internal (subcatchment) functioning. Here, we parameterized SAS functions in a spatially explicit way to understand the internal catchment responses and transport dynamics of reactive dissolved nitrate (N-NO3). The model was applied in a nested mesoscale catchment (457 km2), consisting of a mountainous partly forested, partly agricultural subcatchment, a middle-reach forested subcatchment, and a lowland agricultural subcatchment. The model captured flow and nitrate concentration dynamics not only at the catchment outlet but also at internal gauging stations. Results reveal disparate subsurface mixing dynamics and nitrate export among headwater and lowland subcatchments. The headwater subcatchment has high seasonal variation in subsurface mixing schemes and younger water in discharge, while the lowland subcatchment has less pronounced seasonality in subsurface mixing and much older water in discharge. Consequently, nitrate concentration in discharge from the headwater subcatchment shows strong seasonality, whereas that from the lowland subcatchment is stable in time. The temporally varying responses of headwater and lowland subcatchments alternate the dominant contribution to nitrate export in high and low-flow periods between subcatchments. Overall, our results demonstrate that the spatially explicit SAS modeling provides useful information about internal catchment functioning, helping to develop or evaluate spatial management practices.
Persistent UFZ Identifier https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=25876
Nguyen, V.T., Kumar, R., Musolff, A., Lutz, S.R., Sarrazin, F., Attinger, S., Fleckenstein, J.H. (2022):
Disparate seasonal nitrate export from nested heterogeneous subcatchments revealed with StorAge Selection functions
Water Resour. Res. 58 (3), e2021WR030797