Publication Details |
| Category | Text Publication |
| Reference Category | Journals |
| DOI | 10.1016/j.molliq.2022.118762 |
| Document | author version |
| Title (Primary) | Some mistakes and misinterpretations in the analysis of thermodynamic adsorption data |
| Author | Salvestrini, S.; Ambrosone, L.; Kopinke, F.-D. |
| Source Titel | Journal of Molecular Liquids |
| Year | 2022 |
| Department | TUCHEM |
| Volume | 352 |
| Page From | art. 118762 |
| Language | englisch |
| Topic | T7 Bioeconomy |
| Keywords | Temkin isotherm; van’t Hoff equation; Standard Gibbs adsorption energy; Adsorption spontaneity; Dimensional consistency of equations; Isosteric heat of adsorption |
| Abstract | In this work, we discuss some results and statements recently published in the scientific adsorption literature. In particular, we focus on the thermodynamic aspects of the adsorption process, including dimensional inconsistency of fitted parameters, Temkin isotherm assumptions, inaccurate calculation of ΔH° and ΔS°, parameter determination without providing the errors of estimate, mismatch between selected isotherm models and isosteric heat of adsorption, misleading interpretation of the spontaneity of a process, and interchangeability of ΔG and ΔG°. A graphical method is proposed for assessing data reliability and applicability of the van’t Hoff equation. |
| Persistent UFZ Identifier | https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=25792 |
| Salvestrini, S., Ambrosone, L., Kopinke, F.-D. (2022): Some mistakes and misinterpretations in the analysis of thermodynamic adsorption data J. Mol. Liq. 352 , art. 118762 10.1016/j.molliq.2022.118762 |
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