Publication Details |
Category | Text Publication |
Reference Category | Journals |
DOI | 10.1016/0141-3910(96)00102-4 |
Title (Primary) | Thermal decomposition of biodegradable polyesters—II. Poly(lactic acid) |
Author | Kopinke, F.-D.; Remmler, M.; Mackenzie, K.
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Source Titel | Polymer Degradation and Stability |
Year | 1996 |
Department | TUCHEM; ANA; SAN |
Volume | 53 |
Issue | 3 |
Page From | 329 |
Page To | 342 |
Language | englisch |
Abstract | The thermal decomposition of the biologically degradable polymer poly(lactic acid) (PLA) was investigated by means of several thermoanalytical techniques: thermogravimetry, differential scanning calorimetry, time resolved pyrolysis-MS and pyrolysis-GC/MS. The results mainly confirm reaction mechanisms proposed in the literature. The dominant reaction pathway is an intramolecular transesterification for pure PLA (Tmax = 360 °C), giving rise to the formation of cyclic oligomers. In addition, acrylic acid from cis-elimination as well as carbon oxides and acetaldehyde from fragmentation reactions were detected. PLA samples contaminated with residual Sn from the polymerization process show a preceding selective depolymerization step (Tmax = 300 °C) which produces lactide exclusively. The GC analysis of the oligomers gives insight into the stereochemistry of the original polymer chain with respect to the configuration of the asymmetric C atoms, as well as into the stereochemistry of decomposition reactions. Other experimental findings, which do not fit the proposed reaction mechanisms, are also discussed. |
Persistent UFZ Identifier | https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=24271 |
Kopinke, F.-D., Remmler, M., Mackenzie, K., Möder, M., Wachsen, O. (1996): Thermal decomposition of biodegradable polyesters—II. Poly(lactic acid) Polym. Degrad. Stabil. 53 (3), 329 - 342 10.1016/0141-3910(96)00102-4 |