Publication Details |
| Category | Text Publication |
| Reference Category | Journals |
| DOI | 10.1021/je950142m |
| Title (Primary) | Diffusion coefficients of substituted benzenes at high dilution in water |
| Author | Gabler, T.; Paschke, A.; Schüürmann, G. |
| Source Titel | Journal of Chemical and Engineering Data |
| Year | 1996 |
| Department | OEC; COE |
| Volume | 41 |
| Issue | 1 |
| Page From | 33 |
| Page To | 36 |
| Language | englisch |
| Abstract | The interdiffusion coefficient Daw of six hydrophobic benzene derivatives (a
= chlorobenzene, 1,2-dichlorobenzene, 1,4-dichlorobenzene,
bromobenzene, 1,2-dibromobenzene, 1,4-dibromobenzene) in aqueous
solution (w) at 25 °C is measured at different concentrations below 10-5
solute mole fractions using the Taylor dispersion technique. On the
basis of the experimental uncertainty around 4%, a distinct
concentration dependence is not recognizable. Analysis of the
interdiffusion coefficients with the Stokes−Einstein equation shows
greater
values than expected from the limit of a complete solute−solvent
contact (“stick limit”), and in addition substance-specific deviations.
Chemical engineering correlations for presently available from the literature yield unsatisfactory results for this class of predominantly hydrophobic compounds. |
| Persistent UFZ Identifier | https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=24059 |
| Gabler, T., Paschke, A., Schüürmann, G. (1996): Diffusion coefficients of substituted benzenes at high dilution in water J. Chem. Eng. Data 41 (1), 33 - 36 10.1021/je950142m |
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