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Title (Primary) Comment to the article “Hydroxyl radical scavenging by solid mineral surfaces in oxidative treatment systems: Rate constants and implications” published by K. Rusevova Crincoli and S. G. Huling in Water Research 169, 2020, 115240
Author Kopinke, F.-D.
Journal Water Research
Year 2020
Department TUCHEM
Volume 186
Page From art. 116308
Language englisch
Keywords Radical reactions; Surface scavenging; Mass-transfer limitation; In-situ chemical oxidation
Abstract The fate of radicals in aqueous suspensions can be significantly affected by surfaces scavenging reactions. When short-lived radicals such as •OH are considered, mass-transfer limitation may come into play. Disregarding these limitations may lead to heavy overestimation of surface-mediated reactions. The present comment exposes a potential misinterpretation of experimental data in a recent study with implications for in-situ chemical oxidation (ISCO) techniques.
Persistent UFZ Identifier https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=23542
Kopinke, F.-D. (2020):
Comment to the article “Hydroxyl radical scavenging by solid mineral surfaces in oxidative treatment systems: Rate constants and implications” published by K. Rusevova Crincoli and S. G. Huling in Water Research 169, 2020, 115240
Water Res. 186 , art. 116308