Publication Details |
Category | Text Publication |
Reference Category | Journals |
DOI | 10.1016/j.chroma.2008.05.098 |
Title (Primary) | Aquatic passive sampling of a short-term thiacloprid pulse with the Chemcatcher: impact of biofouling and use of a diffusion-limiting membrane on the sampling rate |
Author | Schäfer, R.B.; Paschke, A.; Liess, M. |
Source Titel | Journal of Chromatography A |
Year | 2008 |
Department | OEC; OEKOTOX |
Volume | 1203 |
Issue | 1 |
Page From | 1 |
Page To | 6 |
Language | englisch |
Keywords | Insecticide; Passive sampler; Runoff; Streams; Pesticide |
Abstract | We examined the performance of the Chemcatcher (University Portsmouth, UK) in two different configurations when used for the aquatic passive sampling of a 1-day pulse contamination with thiacloprid under field-relevant conditions. The configuration without diffusion-limiting membrane led to biofouling of the Empore disk receiving phase resulting in a fourfold reduction in analyte uptake compared to unfouled passive samplers. The sampling rate for the configuration with diffusion-limiting polyethersulfone membrane was also much lower than in a long-term exposure scenario, although no biofouling occurred. Both configurations of the Chemcatcher exhibited high variation in analyte uptake with up to 100% RSD. Short-term contamination events may be underestimated in passive sampling when the receiving phase is biofouled or a diffusion-limiting membrane is employed. |
Persistent UFZ Identifier | https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=1396 |
Schäfer, R.B., Paschke, A., Liess, M. (2008): Aquatic passive sampling of a short-term thiacloprid pulse with the Chemcatcher: impact of biofouling and use of a diffusion-limiting membrane on the sampling rate J. Chromatogr. A 1203 (1), 1 - 6 10.1016/j.chroma.2008.05.098 |