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Title (Primary) Modeling of a thermo-chromatographic pulse (TCP) as radio-frequency (RF)-induced selective heating effect
Author Kraus, M.; Kopinke, F.-D.; Roland, U.
Source Titel Journal of Microwave Power and Electromagnetic Energy
Year 2013
Department TUCHEM
Volume 47
Issue 1
Page From 24
Page To 45
Language englisch
Keywords Radio frequency; selective heating; thermo-chromatographic pulse; model; zeolite
UFZ wide themes RU4;
Abstract By utilizing the specific influence of water adsorption on the dielectric loss factor and,
consequently, selective heating of the zeolite NaY in a radio-frequency (RF) electromagnetic field,
a hot zone moving through the packed bed can be realized initiated by water injection. While the
effect of water adsorption on RF heating and the phenomenon of the thermo-chromatographic
pulse (TCP) itself were described in a previous paper, the present study presents a detailed
model for the description and explanation of this effect. It involves the complex dependence of
dielectric loss on temperature and moisture content, a diffusion model considering both hopping
and Knudsen mechanisms and a power balance for a representative segment of the packed bed.
The developed model was successfully applied to adequately describe various experimental
situations observed for selective RF heating in a NaY zeolite bed.
Persistent UFZ Identifier https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=13547
Kraus, M., Kopinke, F.-D., Roland, U. (2013):
Modeling of a thermo-chromatographic pulse (TCP) as radio-frequency (RF)-induced selective heating effect
J. Microw. Power Electromagn. Energy 47 (1), 24 - 45