Publication Details

Category Text Publication
Reference Category Journals
DOI 10.1016/j.jallcom.2010.07.041
Title (Primary) Semiconducting properties of Ge-doped BaSnO3 ceramic
Author Köferstein, R.; Yakuphanoglu, F.
Source Titel Journal of Alloys and Compounds
Year 2010
Department TUCHEM
Volume 506
Issue 2
Page From 678
Page To 628
Language englisch
Keywords Electrical conductivity; Optical properties; Sintering; Perovskite
Abstract The electrical and optical properties of Ge-doped BaSnO3 ceramics sintered at various temperatures have been investigated to determine their semiconductor behavior. The electrical conductivity of Ge-doped BaSnO3 samples increases with increase in temperature, confirming that the samples exhibit a semiconductor behavior. A maximum conductivity value of 6.31 × 10-9 S/cm was observed for the sample sintered at 1200 °C. The optical band gaps of the Ge-doped BaSnO3 samples were determined by means of reflectance spectra. The variation of optical band gap with temperature was analyzed using Eg(T) = Ego + ßT relation. The rate of change of the band gap ß of BaSn0.99Ge0.01O3 was found to be 7.6 × 10-4 (eV/°C). A minimum optical band gap value of 2.95 eV was observed for the sample sintered at 1400 °C. It is evaluated that BaSn0.99Ge0.01O3 is a wide band gap semiconductor and its semiconducting properties change with sintering temperature.
Persistent UFZ Identifier https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=10192
Köferstein, R., Yakuphanoglu, F. (2010):
Semiconducting properties of Ge-doped BaSnO3 ceramic
J. Alloy. Compd. 506 (2), 678 - 628 10.1016/j.jallcom.2010.07.041