Details zur Publikation

Kategorie Textpublikation
Referenztyp Zeitschriften
DOI 10.1016/j.biortech.2007.09.023
Titel (primär) Chemically modified maize cobs waste with enhanced adsorption properties upon methyl orange and arsenic
Autor Elizalde-González, M.P.; Mattusch, J.; Wennrich, R.
Quelle Bioresource Technology
Erscheinungsjahr 2008
Department ANA
Band/Volume 99
Heft 11
Seite von 5134
Seite bis 5139
Sprache englisch
Keywords Methyl orange; Arsenic; Maize; Chemical modification
Abstract The surface chemistry of maize naturasorbent was altered in this work by the modifying agents: phosphoric acid and different amines (triethanolamine, diethylenetriamine and 1,4-diaminobutane). Removal of methyl orange (25 mg l-1) was <50% by maize corn cobs modified by phosphorylation and higher by the quaternized samples: 68% with the 1,4-diaminobutane and 73% with the diethylenetriamine modificators. Adsorption of arsenite by the samples modified with phosphoric acid/ammonia was 11 µg g-1, which corresponds to 98% removal from a 550 µg As l-1 solution for an adsorbent dose of 50 mg ml-1. The samples modified by phosphoric acid/urea removed 0.4 µg g-1 arsenate from a 300 µg As l-1 solution. Adsorption of methyl orange, arsenite and arsenate was superior by the chemically modified maize cobs judged against the initial naturasorbent. For comparison, removal by the commercial anion exchanger was 100% for methyl orange, 45% (5 µg g-1) for arsenite and 99% (5 µg g-1) for arsenate.
dauerhafte UFZ-Verlinkung https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=903
Elizalde-González, M.P., Mattusch, J., Wennrich, R. (2008):
Chemically modified maize cobs waste with enhanced adsorption properties upon methyl orange and arsenic
Bioresour. Technol. 99 (11), 5134 - 5139 10.1016/j.biortech.2007.09.023