Details zur Publikation |
| Kategorie | Textpublikation |
| Referenztyp | Zeitschriften |
| Titel (primär) | Octanol/water-partitioning of four HCH isomers at 5, 25 and 45 degrees C |
| Autor | Paschke, A.; Schüürmann, G. |
| Quelle | Fresenius Environmental Bulletin |
| Erscheinungsjahr | 1998 |
| Department | OEC; COE |
| Band/Volume | 7 |
| Heft | 5-6 |
| Seite von | 258 |
| Seite bis | 263 |
| Sprache | englisch |
| Abstract | The octanol/water partition coefficient (K-ow) of alpha-, beta-, gamma- and delta-hexachlorocyclohexane (HCH) was determined at 5, 25 and 45 degrees C using the slow-stirring method followed by solid-phase microextraction (SPME) and gas chromatography. The temperature variation of log K-ow is greater between 5 and 25 degrees C (approximate to -0.006 K-1) than from 25 to 45 degrees C (< -0.001 K-1). A preliminary thermodynamic analysis shows that the HCH transfer from water and octanol is slightly exothermic with a gain of entropy. In this respect, no significant differences have been found between the isomers. |
| dauerhafte UFZ-Verlinkung | https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=8902 |
| Paschke, A., Schüürmann, G. (1998): Octanol/water-partitioning of four HCH isomers at 5, 25 and 45 degrees C Fresenius Environ. Bull. 7 (5-6), 258 - 263 |
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