Details zur Publikation

Kategorie Textpublikation
Referenztyp Zeitschriften
DOI 10.1016/S1387-3806(99)00230-4
Titel (primär) Unimolecular ion dissociation and laser-induced coalescence of hydrogenated fullerenes
Autor Möder, M.; Nüchter, M.; Ondruschka, B.; Czira, G.; Vékey, K.; Barrow, M.P.; Drewello, T.
Quelle International Journal of Mass Spectrometry
Erscheinungsjahr 2000
Department ANA
Band/Volume 195/196
Seite von 599
Seite bis 607
Sprache englisch
Keywords Hydrogenated fullerenes; C60H36; Unimolecular dissociation; Tandem mass spectrometry; Coalescence; Laser desorption/ionization
Abstract The ion-fragmentation behaviour of hydrogenated fullerenes has been investigated by tandem mass spectrometry applying sector instrumentation. In addition to the expected loss of hydrogen, unimolecular decay reactions are observed featuring cage rupture by the loss of hydrocarbon moieties. The findings are discussed in comparison with the behaviour of other fullerene derivatives. The gas-phase coalescence reactivity of C60H36 has been studied utilising laser desorption/ionization time-of-flight mass spectrometry. In contrast to pure fullerenes and certain organic fullerene derivatives, hydrogenated fullerenes do not readily undergo laser-induced fusion reactions.
dauerhafte UFZ-Verlinkung https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=7456
Möder, M., Nüchter, M., Ondruschka, B., Czira, G., Vékey, K., Barrow, M.P., Drewello, T. (2000):
Unimolecular ion dissociation and laser-induced coalescence of hydrogenated fullerenes
Int. J. Mass Spectrom. 195/196 , 599 - 607 10.1016/S1387-3806(99)00230-4