Details zur Publikation

Referenztyp Zeitschriften
DOI / URL Link
Titel (primär) Syntheses and characterization of copper complexes of the ligand (2-aminoethyl)bis(2-pyridylmethyl)amine (uns-penp) and derivatives
Autor Schatz, M.; Leibold, M.; Foxon, S.P.; Weitzer, M.; Heinemann, F.W.; Hampel, F.; Walter, O.; Schindler, S.;
Journal / Serie Dalton Transactions
Erscheinungsjahr 2003
Department TUCHEM;
Heft 8
Sprache englisch;
Abstract

Synthesis and structural characterization of the copper(I) and copper(II) complexes of the tripodal tetradentate ligand (2-aminoethyl)bis(2-pyridylmethyl)amine (uns-penp) are reported as well as the reactivity of the copper(I) uns-penp complex towards dioxygen. Uns-penp can be easily modified and two copper(II) complexes of these derivatives have been structurally characterized. In the copper(II) complex of an amide derivative of uns-penp, [Cu(acetyl-uns-penp)Cl]ClO4, it is evident that the amide nitrogen is no longer truly sp(2) hybridised, a consequence of a weak interaction with the copper(II) ion.

ID 5176
dauerhafte UFZ-Verlinkung https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=5176
Schatz, M., Leibold, M., Foxon, S.P., Weitzer, M., Heinemann, F.W., Hampel, F., Walter, O., Schindler, S. (2003):
Syntheses and characterization of copper complexes of the ligand (2-aminoethyl)bis(2-pyridylmethyl)amine (uns-penp) and derivatives
Dalton Trans. (8), 1480 - 1487