Details zur Publikation |
Kategorie | Textpublikation |
Referenztyp | Zeitschriften |
DOI | 10.1007/BF02492097 |
Volltext | Shareable Link |
Titel (primär) | Reaction kinetic monitoring by high performance liquid chromatography coupled to mass spectrometry: oxidation processes of selected isothiazoles |
Autor | Baumann, S.; Möder, M.; Herzschuh, R.; Schulze, B. |
Journal / Serie | Chromatographia |
Erscheinungsjahr | 2003 |
Department | ANA |
Band/Volume | 57 |
Heft | 1 Suppl. |
Seite von | 147 |
Seite bis | 152 |
Sprache | englisch |
Abstract | A HPLC-MS(MS) method is presented here for reaction monitoring of the oxidation of isothiazolium salts with H2O2/acetic acid. The comprehension of this mechanism was the aim of this work using several N-functionalized substances for the investigation. The strong acidic reaction mixture was separated on a RP-18 reversed-phased column without any sample pretreatment and occurring intermediates were identified by API-MS(MS) techniques. Thus, it was possible to gain detailed information about the course of oxidation and to develop an oxidation scheme of existing reaction pathways. |
dauerhafte UFZ-Verlinkung | https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=4705 |
Baumann, S., Möder, M., Herzschuh, R., Schulze, B. (2003): Reaction kinetic monitoring by high performance liquid chromatography coupled to mass spectrometry: oxidation processes of selected isothiazoles Chromatographia 57 (1 Suppl.), 147 - 152 |