Details zur Publikation

Kategorie Textpublikation
Referenztyp Zeitschriften
DOI 10.1002/hyp.70383
Lizenz creative commons licence
Titel (primär) Effects of a perennial drought on nitrate fate in an agriculturally dominated mesoscale catchment as constrained by stable isotope investigations
Autor Mueller, C.; Krieg, R.; Merz, R.; Knöller, K.
Quelle Hydrological Processes
Erscheinungsjahr 2026
Department CATHYD
Band/Volume 40
Heft 1
Seite von e70383
Sprache englisch
Topic T5 Future Landscapes
T4 Coastal System
Keywords climate; drought; extremes; hydrology; nitrate; stable isotopes
Abstract Especially in the years 2018 to 2020, a severe drought was observed in central Germany. To explore the potential impact of this drought on the catchment-scale nitrogen cycling, we investigated the ground- and surface-water compartments of the Holtemme watershed, a mesoscale river catchment in the Harz Mountains, Germany. Analysis of nitrate concentrations and corresponding isotope signatures for groundwater and surface water samples was conducted throughout the drought period and continued until discharge conditions returned to the long-term mean in early 2021. The study revealed a pronounced decline in nitrate concentrations in both compartments during the drought, with groundwater showing an average reduction of ~60%, and surface water exhibiting a wide range of changes from +32% to −59% (mid- and downstream decreasing from 19.4 to 2.3 mg L−1). In the post-drought period, surface-water nitrate concentrations increased sharply, reaching values up to 18.3 mg L−1. Isotope investigations allowed us to distinguish between different nitrate sources and microbial turnover processes. Time series analysis of δ15N–NO3 showed regular oscillations within the year ranging from 2‰ to 20‰ (AIR), illustrating a periodic organic fertiliser applications. Corresponding δ18O–NO3 signatures showed higher, seasonally independent variations, with a mean of 6‰ (VSMOW), which can be explained by the expected isotope variability of the ambient water during nitrification. However, flow paths for nitrate mobilisation into the surface water appear to be unaffected by the drought, as the contributions of each nitrate source decreased equally during the dry period. Nitrate concentrations increased markedly after the drought, regardless of the recent nitrate supply, reaching values of up to 20 mg L−1 in 2022.
dauerhafte UFZ-Verlinkung https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=31858
Mueller, C., Krieg, R., Merz, R., Knöller, K. (2026):
Effects of a perennial drought on nitrate fate in an agriculturally dominated mesoscale catchment as constrained by stable isotope investigations
Hydrol. Process. 40 (1), e70383 10.1002/hyp.70383