Details zur Publikation

Kategorie Textpublikation
Referenztyp Zeitschriften
DOI 10.1016/j.envpol.2005.12.046
Titel (primär) Comparative application of solid-phase microextraction fibre assemblies and semi-permeable membrane devices as passive air samplers for semi-volatile chlorinated organic compounds. A case study on the landfill "Grube Antonie" in Bitterfeld, Germany
Autor Paschke, A.; Vrana, B.; Popp, P.; Schüürmann, G.
Quelle Environmental Pollution
Erscheinungsjahr 2006
Department OEC; ANA
Band/Volume 144
Heft 2
Seite von 414
Seite bis 422
Sprache englisch
Keywords Solid-phase microextraction (SPME); Semi-permeable membrane device (SPMD); Passive sampling; Chlorobenzenes; Hexachlorocyclohexane isomers; DDT
Abstract Solid phase microextraction (SPME) fibres coated with Carbowax/divinylbenzene and semi-permeable membrane devices (SPMDs) of standard configuration were used to obtain time-weighted average (TWA) field air concentrations of selected chlorinated semi-volatile compounds on a landfill, where large amounts of lindane by-products were deposited, together with other hazardous chemical residues in the past. Additionally, spot sampling with SPME fibres was performed to identify the emission hotspot and sampling rates were determined/predicted for the substances of interest. Both samplers yield comparable TWA air concentrations of lindane and its isomers and of DDT with its metabolites and gain in certainty about the landfill as remaining source of air pollution with these compounds in the region. Both SPME fibres and SPMDs (respective their modifications) can be recommended as sampling tools in process studies and larger air monitoring programmes. However, further calibration studies and field tests are necessary to obtain reliable sampling rates for a wider range of semi-volatile compounds.
dauerhafte UFZ-Verlinkung https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=2909
Paschke, A., Vrana, B., Popp, P., Schüürmann, G. (2006):
Comparative application of solid-phase microextraction fibre assemblies and semi-permeable membrane devices as passive air samplers for semi-volatile chlorinated organic compounds. A case study on the landfill "Grube Antonie" in Bitterfeld, Germany
Environ. Pollut. 144 (2), 414 - 422 10.1016/j.envpol.2005.12.046