Details zur Publikation |
| Kategorie | Textpublikation |
| Referenztyp | Zeitschriften |
| DOI | 10.1016/j.chroma.2005.12.092 |
| Titel (primär) | Separation of technical 4-nonylphenols and their biodegradation products by comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry |
| Autor | Moeder, M.; Martin, C.; Schlosser, D.
; Harynuk, J.; Górecki, T. |
| Quelle | Journal of Chromatography A |
| Erscheinungsjahr | 2006 |
| Department | UMB; ANA |
| Band/Volume | 1107 |
| Heft | 1-2 |
| Seite von | 233 |
| Seite bis | 239 |
| Sprache | englisch |
| Keywords | 4-Nonylphenols; Metabolites; GC × GC–TOF-MS |
| Abstract | Comprehensive two-dimensional gas chromatography (GC × GC) coupled to time-of-flight mass spectrometry (TOF-MS) was applied to improve the separation of 4-nonylphenol isomers and their biodegradation products. The structurally similar nonylphenol isomers were separated by combining a 30 m long semi-polar column and a short polar capillary. Both were coupled via a custom-made liquid nitrogen cryogenic modulator. The advanced GC resolution of coeluting isomers, additionally supported by fast scanning TOF-MS, provided clearer, non-interfered mass spectra of individual isomers. Thus, identification of components is facilitated as shown for isomeric 4-nonylphenols and metabolites of their biodegradation by Clavariopsis aquatica, an aquatic fungus. GC × GC–TOF-MS analysis enabled the separation of about 40 alkylphenol isomers included in technical 4-nonylphenol. During biodegradation the variety of emerging compounds increased with longer reaction time. The comprehensive analysis indicated a broad spectrum of hydroxylated, carboxylated nonylphenolisomers and additionally, chlorinated aromatic compounds produced and released from the fungal culture. |
| dauerhafte UFZ-Verlinkung | https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=2875 |
| Moeder, M., Martin, C., Schlosser, D., Harynuk, J., Górecki, T. (2006): Separation of technical 4-nonylphenols and their biodegradation products by comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry J. Chromatogr. A 1107 (1-2), 233 - 239 10.1016/j.chroma.2005.12.092 |
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