Details zur Publikation

Kategorie Textpublikation
Referenztyp Zeitschriften
DOI 10.1002/bbpc.19930970909
Titel (primär) Diffusion coefficients, viscosities and densities in the binary subsystems of Methyl isopropyl ketone-n-Butyl acetate-Water
Autor Thiel, P.; Paschke, A.; Winkelmann, J.
Quelle Berichte der Bunsen-Gesellschaft für physikalische Chemie
Erscheinungsjahr 1993
Department OEC; COE
Band/Volume 97
Heft 9
Seite von 1119
Seite bis 1124
Sprache englisch
Abstract

The concentration dependence of mutual diffusion coefficients, kinematic viscosities and densities in the binary systems Methyl isopropyl ketone (Mipk)-n-Butyl acetate (Buac), Buac-Water and Mipk-Water is determined at 288.15 K, 293.15 K and 298.16 K. Diffusion coefficients at infinite dilution were extrapolated from the experimental data.

Only in the completely miscible system Mipk-Buac were the heat of mixing at 297.76 K and vapour-liquid equilibrium data at 323.15 K and 343.15 K measured and parameters for the NRTL-equation calculated. In the system Mipk-water with limited miscibility, the NRTL-parameters were obtained from liquid-liquid equilibrium data. Using our values at infinite dilution the concentration dependence of the mutual diffusion coefficients can be satisfactorily predicted by the Caldwell/Babb correlation.

dauerhafte UFZ-Verlinkung https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=27907
Thiel, P., Paschke, A., Winkelmann, J. (1993):
Diffusion coefficients, viscosities and densities in the binary subsystems of Methyl isopropyl ketone-n-Butyl acetate-Water
Ber. Bunsenges. Phys. Chem. 97 (9), 1119 - 1124 10.1002/bbpc.19930970909