Details zur Publikation |
Kategorie | Textpublikation |
Referenztyp | Zeitschriften |
DOI | 10.1021/ie00013a009 |
Titel (primär) | Relative rates of coke formation from hydrocarbons in steam cracking of naphtha. 2. Paraffins, naphthenes, mono-, di-, and cycloolefins, and acetylenes |
Autor | Kopinke, F.-D.; Zimmermann, G.; Reyniers, G.C.; Froment, F. |
Quelle | Industrial & Engineering Chemistry Research |
Erscheinungsjahr | 1993 |
Department | SAN |
Band/Volume | 32 |
Heft | 1 |
Seite von | 56 |
Seite bis | 61 |
Sprache | englisch |
Abstract | Relative rate constants of coke formation from saturated hydrocarbons, olefins, and acetylenes during steam cracking of naphtha at 810 C were determined by application of [sup 14]C-labeled compounds. The range of hydrocarbons investigated comprises 20 representatives of paraffins, from methane to hexadecane, and of naphthenes, from cyclopentane to hydroanthracene, and 20 olefins from ethene to styrene, including cyclo- and diolefins, and five acetylenes. Carbonaceous deposits in pyrolysis reactors from steel and quartz as well as in the transfer line exchange (TLE) section were determined separately. |
dauerhafte UFZ-Verlinkung | https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=27879 |
Kopinke, F.-D., Zimmermann, G., Reyniers, G.C., Froment, F. (1993): Relative rates of coke formation from hydrocarbons in steam cracking of naphtha. 2. Paraffins, naphthenes, mono-, di-, and cycloolefins, and acetylenes Ind. Eng. Chem. Res. 32 (1), 56 - 61 10.1021/ie00013a009 |