Details zur Publikation

Kategorie Textpublikation
Referenztyp Zeitschriften
DOI 10.1021/ie00013a009
Titel (primär) Relative rates of coke formation from hydrocarbons in steam cracking of naphtha. 2. Paraffins, naphthenes, mono-, di-, and cycloolefins, and acetylenes
Autor Kopinke, F.-D.; Zimmermann, G.; Reyniers, G.C.; Froment, F.
Quelle Industrial & Engineering Chemistry Research
Erscheinungsjahr 1993
Department SAN
Band/Volume 32
Heft 1
Seite von 56
Seite bis 61
Sprache englisch
Abstract Relative rate constants of coke formation from saturated hydrocarbons, olefins, and acetylenes during steam cracking of naphtha at 810 C were determined by application of [sup 14]C-labeled compounds. The range of hydrocarbons investigated comprises 20 representatives of paraffins, from methane to hexadecane, and of naphthenes, from cyclopentane to hydroanthracene, and 20 olefins from ethene to styrene, including cyclo- and diolefins, and five acetylenes. Carbonaceous deposits in pyrolysis reactors from steel and quartz as well as in the transfer line exchange (TLE) section were determined separately.
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Kopinke, F.-D., Zimmermann, G., Reyniers, G.C., Froment, F. (1993):
Relative rates of coke formation from hydrocarbons in steam cracking of naphtha. 2. Paraffins, naphthenes, mono-, di-, and cycloolefins, and acetylenes
Ind. Eng. Chem. Res. 32 (1), 56 - 61 10.1021/ie00013a009