Details zur Publikation |
Kategorie | Textpublikation |
Referenztyp | Zeitschriften |
DOI | 10.1080/00211919408046739 |
Titel (primär) | Methodische Untersuchungen zum 15N-ConFlo-IRMS-System. Methodical studies of 15N-ConFlo-IRMS-technique |
Autor | Gehre, M.; Hofmann, D.; Weigel, P. |
Quelle | Isotopenpraxis |
Erscheinungsjahr | 1994 |
Department | ISOBIO; OEC; COE |
Band/Volume | 30 |
Heft | 2-3 |
Seite von | 239 |
Seite bis | 245 |
Sprache | englisch |
Keywords | Methodology; nitrogen 15; natural abundances; on-line-IRMS |
Abstract | After installing a C-GC-IRMS-System (Elemental analyzer EA 1108 CHN + IRMS MAT 252) some problems arose with respect to the external precision of the δ15N values (standard deviation approx. 1‰ at < 50 μg N) after changeover from 13C to 15N measurements. Attempts were made to determine the reasons for these effects and to eliminate them by changes of the Carlo Erba on-line combustion system (EA) and the split. Non-quantifiable contributions, e.g., air nitrogen and/or N2 in carrier gas helium were reduced by a blank correction. Using Cyclohexanone-2, 4-dinitrophenylhydrazone it was shown that under the same conditions and after a common blank correction with small and large amounts of samples (60-650 μg, 20% N) an external precision of 0.2‰ (standard deviation, 10 cycles) can be reached. |
dauerhafte UFZ-Verlinkung | https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=27735 |
Gehre, M., Hofmann, D., Weigel, P. (1994): Methodische Untersuchungen zum 15N-ConFlo-IRMS-System. Methodical studies of 15N-ConFlo-IRMS-technique Isotopenpraxis 30 (2-3), 239 - 245 10.1080/00211919408046739 |