Details zur Publikation |
| Kategorie | Textpublikation |
| Referenztyp | Zeitschriften |
| DOI | 10.1016/j.poly.2005.10.021 |
| Titel (primär) | Structures of racemic lithium tartrate hydrates |
| Autor | Gelbrich, T.; Threlfall, T.L.; Huth, S.; Seeger, E. |
| Quelle | Polyhedron |
| Erscheinungsjahr | 2006 |
| Department | UBT |
| Band/Volume | 25 |
| Heft | 4 |
| Seite von | 937 |
| Seite bis | 944 |
| Sprache | englisch |
| Abstract | Racemic dimetal tartrate hydrates were obtained from the reaction of D,L-tartaric acid with LiOH and MOH, where M = Li, Na, K, Rb, Cs, NH4. Dilithium trihydrate Li-2(C4H4O6) center dot 3H(2)O (1) consists of two distinct two-dimensional coordination networks [Li-6(C4H4O6)(3)(H2O)(9)](n) (A) and [Li-2(C4H4O6)(H2O)(3)](2n) (B) which are arranged parallel in BAABAA fashion. Lithium sodium dihydrate LiNa(C4H4O6) center dot 2H(2)O (2) is as a three-dimensional coordination network in which discrete centrosymmetric [Li(C4H4O6)(H2O)](2) units are linked by NaO6 polyhedra. The monohydrates LiM(C4H4O6) center dot H2O with M = K (3), Rb (4), Cs (5) are three-dimensional coordination networks which are isostructural with the hydrogen-bonded ammonium analogue, M = NH4 (6). These structures are composed of [LiM(C4H4O6)(H2O)](n) layers linked by MO8 and MO10 polyhedra. Different patterns of hydrogen bonding between tartrate ions and water molecules are observed in structures 1, 2 and the series of 3-6. (c) 2005 Elsevier Ltd. All rights reserved |
| dauerhafte UFZ-Verlinkung | https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=2629 |
| Gelbrich, T., Threlfall, T.L., Huth, S., Seeger, E. (2006): Structures of racemic lithium tartrate hydrates Polyhedron 25 (4), 937 - 944 10.1016/j.poly.2005.10.021 |
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