Details zur Publikation

Kategorie Textpublikation
Referenztyp Zeitschriften
DOI 10.1007/s00769-006-0205-x
Volltext Shareable Link
Titel (primär) Test for non-linearity concerning linear calibrated chemical measurements
Autor Brüggemann, L.; Quapp, W.; Wennrich, R.
Quelle Accreditation and Quality Assurance
Erscheinungsjahr 2006
Department ANA; SANA
Band/Volume 11
Heft 12
Seite von 625
Seite bis 631
Sprache englisch
Keywords Linear calibration; Non-linearity
Abstract Linear calibrated chemical measurements are based on the assumption of linearity. Due to influences of matrices at real samples the condition of linearity can be violated. Therefore, a profound examination has to attach much importance on the linearity of calibration. However, different procedures have been applied for this purpose in literature. In order to examine linear calibration for non-linearity, a recently presented procedure is compared with conventional techniques. The associated statistical models and estimations are represented. The applicability of the different procedures is demonstrated in some practical examples, the determination of arsenic in surface water samples taken from different sites in abandoned mining areas in central Germany. Recommendations for using the indicators and tests of non-linearity are given.
dauerhafte UFZ-Verlinkung https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=2553
Brüggemann, L., Quapp, W., Wennrich, R. (2006):
Test for non-linearity concerning linear calibrated chemical measurements
Accredit. Qual. Assur. 11 (12), 625 - 631 10.1007/s00769-006-0205-x