Details zur Publikation

Kategorie Textpublikation
Referenztyp Zeitschriften
DOI 10.1016/j.apcatb.2015.12.043
Titel (primär) Efforts for long-term protection of palladium hydrodechlorination catalysts
Autor Comandella, D.; Woszidlo, S.; Georgi, A.; Kopinke, F.-D.; Mackenzie, K. ORCID logo
Quelle Applied Catalysis B-Environmental
Erscheinungsjahr 2016
Department TUCHEM
Band/Volume 186
Seite von 204
Seite bis 211
Sprache englisch
Keywords Pd hydrodechlorination catalysts; Catalyst coating; Catalyst deactivation; Catalyst long-term activity; Water treatment
UFZ Querschnittsthemen RU3;

Nano-sized palladium (Pd) catalysts are known for their high intrinsic hydrodechlorination (HDC) activity towards many chlorinated water pollutants, converting them into non-harmful compounds. Optimization of catalyst protection by embedding various types of Pd catalysts (Pd on oxidic supports and in-situ generated Pd clusters) into poly(dimethylsiloxane) (PDMS) layers was studied together with their use in HDC reactions. The catalyst performance in standard batch and long-term experimental set-ups was used to better understand and optimize the Pd-PDMS system. The phenomenon of polymer deterioration by entrapped HDC-generated HCl is studied for various systems and found to be the main reason for limited life times of Pd-PDMS systems.

Pd-PDMS composites were found to provide long-term protection from ionic catalyst poisons. This gain in prolonged catalyst protection goes along with an inevitable decrease in specific catalyst activity which is unhesitantly accepted for the benefit of a longer-lasting catalytic activity. However, when comparing the relative loss of the specific Pd activity due to embedding, it is found to be much lower for initially less active catalyst particles (e.g. a factor of 2 for Pd/Al2O3) compared to about two orders of magnitude for the highly active nanoscale Pd particles. It could be shown that embedded catalysts in continuously operated long-term set-ups have enhanced resistance and longevity compared to those tested in repeated batch-type reaction cycles. PDMS-embedded Pd/Al2O3 maintains its full initial activity up to turnover numbers of >750 (for trichloroethene as probe substance), whereas the catalyst system loses more than 50% of its initial activity for a comparable catalyst utilization (TON ≈ 750) operated in batch cycles.

dauerhafte UFZ-Verlinkung
Comandella, D., Woszidlo, S., Georgi, A., Kopinke, F.-D., Mackenzie, K. (2016):
Efforts for long-term protection of palladium hydrodechlorination catalysts
Appl. Catal. B-Environ. 186 , 204 - 211 10.1016/j.apcatb.2015.12.043