Details zur Publikation

Kategorie Textpublikation
Referenztyp Zeitschriften
DOI 10.1021/es070807s
Titel (primär) Passive sampler for combined chemical and toxicological long-term monitoring of groundwater: the ceramic toximeter
Autor Bopp, S.K.; McLachlan, M.S.; Schirmer, K.
Quelle Environmental Science & Technology
Erscheinungsjahr 2007
Department ZELLTOX
Band/Volume 41
Heft 19
Seite von 6868
Seite bis 6876
Sprache englisch
Abstract We present the development of a passive sampling device that combines chemical with biological assessment of water following time-integrating, long-term sampling. The new device, which was designated the Ceramic Toximeter, brings together the simplicity of the Ceramic Dosimeter as a ceramic membrane-based, solid-sorbent sampler and the uniqueness of a recently developed solid-phase, solvent-free bioassay. In this bioassay, Biosilon, i.e., polystyrene polymer beads, is used to present sorbed contaminants to vertebrate cells that adhere to the contaminant-loaded Biosilon and respond. Focusing on Biosilon as sorbent, its ability to accumulate 16 polycyclic aromatic hydrocarbons (PAHs) was explored. When tested up to 42 days in the laboratory or 1 year in groundwater at a contaminated gasworks site, Biosilon-filled Ceramic Toximeters yielded back-calculated time-weighted average aqueous PAH concentrations that agreed well with concentrations obtained by frequent snapshot sampling. The chosen bioassay response, the induction of 7-ethoxyresorufin-O-deethylase, was as predicted in the laboratory setting but could only partly be explained by the analyzed PAHs in the field. Based on this first assessment, the Ceramic Toximeter emerges as a resource efficient water monitoring device with a variety of potential future applications.
dauerhafte UFZ-Verlinkung https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=1664
Bopp, S.K., McLachlan, M.S., Schirmer, K. (2007):
Passive sampler for combined chemical and toxicological long-term monitoring of groundwater: the ceramic toximeter
Environ. Sci. Technol. 41 (19), 6868 - 6876 10.1021/es070807s