Details zur Publikation

Kategorie Textpublikation
Referenztyp Zeitschriften
DOI 10.1021/es502437e
Titel (primär) First day of an oil spill on the open sea: Early mass transfers of hydrocarbons to air and water
Autor Gros, J.; Nabi, D.; Würz, B.; Wick, L.Y.; Brussaard, C.P.D.; Huisman, J.; van der Meer, J.R.; Reddy, C.M.; Arey, J.S.
Quelle Environmental Science & Technology
Erscheinungsjahr 2014
Department UMB
Band/Volume 48
Heft 16
Seite von 9400
Seite bis 9411
Sprache englisch
UFZ Querschnittsthemen RU3;

During the first hours after release of petroleum at sea, crude oil hydrocarbons partition rapidly into air and water. However, limited information is available about very early evaporation and dissolution processes. We report on the composition of the oil slick during the first day after a permitted, unrestrained 4.3 m3 oil release conducted on the North Sea. Rapid mass transfers of volatile and soluble hydrocarbons were observed, with >50% of ≤C17 hydrocarbons disappearing within 25 h from this oil slick of <10 km2 area and <10 μm thickness. For oil sheen, >50% losses of ≤C16 hydrocarbons were observed after 1 h. We developed a mass transfer model to describe the evolution of oil slick chemical composition and water column hydrocarbon concentrations. The model was parametrized based on environmental conditions and hydrocarbon partitioning properties estimated from comprehensive two-dimensional gas chromatography (GC×GC) retention data. The model correctly predicted the observed fractionation of petroleum hydrocarbons in the oil slick resulting from evaporation and dissolution. This is the first report on the broad-spectrum compositional changes in oil during the first day of a spill at the sea surface. Expected outcomes under other environmental conditions are discussed, as well as comparisons to other models.

dauerhafte UFZ-Verlinkung
Gros, J., Nabi, D., Würz, B., Wick, L.Y., Brussaard, C.P.D., Huisman, J., van der Meer, J.R., Reddy, C.M., Arey, J.S. (2014):
First day of an oil spill on the open sea: Early mass transfers of hydrocarbons to air and water
Environ. Sci. Technol. 48 (16), 9400 - 9411 10.1021/es502437e