Publication Details |
Category | Text Publication |
Reference Category | Journals |
DOI | 10.1039/b208740e |
Title (Primary) | Syntheses and characterization of copper complexes of the ligand (2-aminoethyl)bis(2-pyridylmethyl)amine (uns-penp) and derivatives |
Author | Schatz, M.; Leibold, M.; Foxon, S.P.; Weitzer, M.; Heinemann, F.W.; Hampel, F.; Walter, O.; Schindler, S. |
Source Titel | Dalton Transactions |
Year | 2003 |
Department | TUCHEM |
Issue | 8 |
Page From | 1480 |
Page To | 1487 |
Language | englisch |
Abstract | Synthesis and structural characterization of the copper(I) and copper(II) complexes of the tripodal tetradentate ligand (2-aminoethyl)bis(2-pyridylmethyl)amine (uns-penp) are reported as well as the reactivity of the copper(I) uns-penp complex towards dioxygen. Uns-penp can be easily modified and two copper(II) complexes of these derivatives have been structurally characterized. In the copper(II) complex of an amide derivative of uns-penp, [Cu(acetyl-uns-penp)Cl]ClO4, it is evident that the amide nitrogen is no longer truly sp(2) hybridised, a consequence of a weak interaction with the copper(II) ion. |
Persistent UFZ Identifier | https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=5176 |
Schatz, M., Leibold, M., Foxon, S.P., Weitzer, M., Heinemann, F.W., Hampel, F., Walter, O., Schindler, S. (2003): Syntheses and characterization of copper complexes of the ligand (2-aminoethyl)bis(2-pyridylmethyl)amine (uns-penp) and derivatives Dalton Trans. (8), 1480 - 1487 10.1039/b208740e |