Publication Details |
Category | Text Publication |
Reference Category | Book chapters |
DOI | 10.1016/S0167-2991(97)80855-5 |
Title (Primary) | Electronic effects of hydrogen spillover on titania |
Title (Secondary) | Spillover and migration of surface species on catalysts. Proceedings of the 4th International Conference on Spillover, Dalian, China, September 15-18, 1997 |
Author | Roland, U.; Salzer, R.; Sümmchen, L. |
Publisher | Li, C.; Xin, Q. |
Source Titel | Studies in Surface Science and Catalysis |
Year | 1997 |
Department | SAN |
Volume | 112 |
Page From | 339 |
Page To | 348 |
Language | englisch |
Abstract | Investigations on the interaction of hydrogen with platinum-containing titania have shown that the adsorption of spilt-over hydrogen (H*) species is connected with a partial electron transfer from H* to TiO2. The experimental results depict an enhanced n-type conductivity as well as a formation of neutral oxygen vacancies (V-OX(X)) from singly ionized vacancies (V-OX(+)) in the surface region of the semiconducting metal oxide. The influence on the electronic state of the oxygen vacancies was concluded from fluorescence measurements by means of FT NIR Raman spectroscopy |
Persistent UFZ Identifier | https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=9577 |
Roland, U., Salzer, R., Sümmchen, L. (1997): Electronic effects of hydrogen spillover on titania In: Li, C., Xin, Q. (eds.) Spillover and migration of surface species on catalysts. Proceedings of the 4th International Conference on Spillover, Dalian, China, September 15-18, 1997 Studies in Surface Science and Catalysis 112 Elsevier, p. 339 - 348 10.1016/S0167-2991(97)80855-5 |