Publication Details

Category Text Publication
Reference Category Journals
DOI 10.1016/S1387-3806(99)00230-4
Title (Primary) Unimolecular ion dissociation and laser-induced coalescence of hydrogenated fullerenes
Author Möder, M.; Nüchter, M.; Ondruschka, B.; Czira, G.; Vékey, K.; Barrow, M.P.; Drewello, T.
Source Titel International Journal of Mass Spectrometry
Year 2000
Department ANA
Volume 195/196
Page From 599
Page To 607
Language englisch
Keywords Hydrogenated fullerenes; C60H36; Unimolecular dissociation; Tandem mass spectrometry; Coalescence; Laser desorption/ionization
Abstract The ion-fragmentation behaviour of hydrogenated fullerenes has been investigated by tandem mass spectrometry applying sector instrumentation. In addition to the expected loss of hydrogen, unimolecular decay reactions are observed featuring cage rupture by the loss of hydrocarbon moieties. The findings are discussed in comparison with the behaviour of other fullerene derivatives. The gas-phase coalescence reactivity of C60H36 has been studied utilising laser desorption/ionization time-of-flight mass spectrometry. In contrast to pure fullerenes and certain organic fullerene derivatives, hydrogenated fullerenes do not readily undergo laser-induced fusion reactions.
Persistent UFZ Identifier https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=7456
Möder, M., Nüchter, M., Ondruschka, B., Czira, G., Vékey, K., Barrow, M.P., Drewello, T. (2000):
Unimolecular ion dissociation and laser-induced coalescence of hydrogenated fullerenes
Int. J. Mass Spectrom. 195/196 , 599 - 607 10.1016/S1387-3806(99)00230-4