Publication Details

Category Text Publication
Reference Category Journals
DOI 10.1007/BF02492097
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Title (Primary) Reaction kinetic monitoring by high performance liquid chromatography coupled to mass spectrometry: oxidation processes of selected isothiazoles
Author Baumann, S.; Möder, M.; Herzschuh, R.; Schulze, B.
Source Titel Chromatographia
Year 2003
Department ANA
Volume 57
Issue 1 Suppl.
Page From 147
Page To 152
Language englisch
Abstract

A HPLC-MS(MS) method is presented here for reaction monitoring of the oxidation of isothiazolium salts with H2O2/acetic acid. The comprehension of this mechanism was the aim of this work using several N-functionalized substances for the investigation. The strong acidic reaction mixture was separated on a RP-18 reversed-phased column without any sample pretreatment and occurring intermediates were identified by API-MS(MS) techniques. Thus, it was possible to gain detailed information about the course of oxidation and to develop an oxidation scheme of existing reaction pathways.

Persistent UFZ Identifier https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=4705
Baumann, S., Möder, M., Herzschuh, R., Schulze, B. (2003):
Reaction kinetic monitoring by high performance liquid chromatography coupled to mass spectrometry: oxidation processes of selected isothiazoles
Chromatographia 57 (1 Suppl.), 147 - 152 10.1007/BF02492097