Details zur Publikation

Kategorie Textpublikation
Referenztyp Zeitschriften
DOI 10.1016/S0926-860X(00)00524-X
Titel (primär) Influence of spilt-over hydrogen on the electrical properties of H-ZSM-5
Autor Franke, M.E.; Simon, U.; Rößner, F.; Roland, U.
Quelle Applied Catalysis A-General
Erscheinungsjahr 2000
Department TUCHEM; SAN
Band/Volume 202
Seite von 179
Seite bis 182
Sprache englisch
Keywords Spill-over hydrogen; Zeolites; Pt/H-ZSM-5; Electrical properties; Impedance spectroscopy
Abstract In this work the effect of H2 on the electrical properties of H-ZSM-5 and Pt/H-ZSM-5 has been studied applying impedance spectroscopy in order to clarify the nature of migrating H* species (charged or uncharged, atomic or molecular) in the spillover process. The observed drop of the resistive part of a charge carrier relaxation process is attributed to the increase of mobile charges in the zeolite. This can be explained in terms of the dissociation of hydrogen on the Pt nanoparticles, the subsequent diffusion onto the zeolitic support and the formation of H+ as migrating species.
dauerhafte UFZ-Verlinkung https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=7135
Franke, M.E., Simon, U., Rößner, F., Roland, U. (2000):
Influence of spilt-over hydrogen on the electrical properties of H-ZSM-5
Appl. Catal. A-Gen. 202 , 179 - 182 10.1016/S0926-860X(00)00524-X