Details zur Publikation |
| Referenztyp | Zeitschriften |
| DOI / URL | Link |
| Titel (primär) | Koenigs-Knorr synthesis of cycloalkyl glycosides |
| Autor | Wimmer, Z.; Pechová, L.; Saman, D.; |
| Journal / Serie | Molecules |
| Erscheinungsjahr | 2004 |
| Department | UBT; UBZ; |
| Band/Volume | 9 |
| Heft | 11 |
| Sprache | englisch; |
| Keywords | Koenigs-Knorr synthesis; Cycloalkyl-β-D-glucopyranosides; Cycloalkyl-β- D-galactopyranosides; Cadmium carbonate |
| Abstract | Cadmium carbonate was found to be a useful promoter in the Koenigs-Knorrsynthesis of 2-(4-methoxybenzyl)cyclohexyl-β-D-glycopyranosides. Using this promotermodel glucoside and galactoside derivatives of cyclic (i.e., secondary) alcohols weresynthesized in 50–60 % overall yields. Diastereoisomeric mixtures of products wereobtained in these syntheses, which started from racemic isomers of 2-(4-methoxy-benzyl)cyclohexanol. The prepared compounds have been purified and characterized bytheir 1H- and 13C-NMR spectra, as well as by their IR and MS spectra, in order to usethem as reference compounds in planned subsequent research. |
| ID | 4659 |
| dauerhafte UFZ-Verlinkung | https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=4659 |
| Wimmer, Z., Pechová, L., Saman, D. (2004): Koenigs-Knorr synthesis of cycloalkyl glycosides Molecules 9 (11), 902 - 912 |
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